Page 26 - Steel Tech India eMagazine Volume April 2022
P. 26

VOL. 16 • NO. 3 • April 2022

                 roll crusher and further grinded through a ball mill to a   Wave length dispersive X-ray fluorescence (WDXRF)
                 homogeneous size.                                  analysis  in  PAN  analytical.  For  the  waste  dusts
                 Characterization of Raw Materials                  proximate analysis is performed.
                 Sample less than 75 micron is subjected to X-ray   a)  Sinter Plant Dust
                 diffraction (XRD) analysis for phase determination in
                 Rigaku Ultima III with the help of cu-K radiation and   XRD Analysis


























                                        (i)                                               (ii)
                 Fig. 3:  i) X-ray diffraction analysis plot for sinter plant air cleaning chamber (ACP) dust
                              ii) X-ray diffraction analysis plot for sinter plant gas cleaning chamber (GCP) dust

                 the above XRD plot shows, sinter plant dust contains hematite (Fe O ) as major phase. the dust collected from
                                                                             2  3
                 sinter plant air cleaning chamber contains silica (SiO ) and lime (caO) as other prominent peaks whereas dust
                                                                 2
                 from sinter plant gas cleaning chamber contains silica (SiO ) and magnetite (Fe O ) as minor prominent peaks.
                                                                      2                  3  4
                 this means that hematite is the major mineral phase present in sinter plant dust and iron (Fe) is the element which
                 can be extracted from these dusts.
                 WDXRF Analysis

                 Table 1: Showing the WDXRF analysis data of sinter plant dusts

                   Sl      Name of                                Chemical Composition (%)
                   no.      Sample
                                           T.Fe     SiO 2     Al O 3   P O 5       S       Mn       CaO       MgO
                                                                         2
                                                               2
                    1   Sinter AcP Dust   39.876    7.672    3.918     0.133     0.258    0.088    13.695     2.193
                    2   Sinter GcP Dust   40.849    9.981     3.62     0.104     0.584    0.096    10.696     2.307

                 Waste dusts from sinter plant contain total iron around 40 %, silica around 10 %, lime around 12 % and other
                 elements & compounds are in traceable amount as shown in the above table.

                 Proximate Analysis
                 carbon content in sinter plant AcP dust is 2 % and in sinter plant GcP dust is 2.75 %.
                 b) SMS Sludge

                 XRD Analysis


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